Any way to connect a PS5 to an Oculus Quest 2 and use it to play?
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Yes, you can connect a PS5 to an Oculus Quest 2 to play games. You’ll need to use a sideloaded app like Chiaki or PS Remote Play apk. However, keep in mind that this isn’t officially supported by Sony or Oculus, so your experience may vary. Enjoy your gaming! 
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Yes by using the third-party software that you have mentioned
To stream PS5 games to your PC and then use Oculus Link to play them on your Quest 2.
There is no other way…
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If the PS5 can use remote play via the Android app, it might be possible to sideload it.
The Oculus Quest 2 is all-in-one! You don’t need any extra equipment to play VR games on it. But, it won’t work with Playstation VR or connect to a PS4/PS5. However, you can connect it to a computer and use SteamVR for even more games.